Hydrochemistry of an ancient traditional irrigation reservoir in Padaviya,Sri Lanka

Padaviya Wewa Reservoir constructed in 2nd century BC is an important traditional reservoir in Sri Lanka. The construction and the use of these traditional Sri Lankan reservoirs are different from modern large-scale hydroelectric and multi-purpose reservoirs in Sri Lanka and the rest of the world. The hydrochemistry of these unique water bodies has been rarely studied and understood. In this study, depth-wise distribution of Fe, Mn, Zn, Cd, and As and their correlation with pH, dissolved oxygen, conductivity, temperature, BOD, COD, and total phosphate were investigated to identify the mechanisms that drive the water quality in Padaviya Wewa Reservoir. There is a well distinguishable chemical gradient from the surface to the bottom of the water column suggesting that Padaviya is not a well-mixed water body even though the maximum water depth during the study period was 4.75 m. There was a strong negative correlation between Fe, Mn, Zn, and Cd and DO in both surface and bottom waters. In addition, a strong positive correlation between Fe, Mn, Zn, Cd, and As, and total phosphate was observed in bottom waters. The suggested driving force behind the depth-wise distribution of chemical species is intense biological activities in the reservoir. The weak thermal stratification is strengthened by photosynthesis at the surface waters and organic matter degradation at bottom of the reservoir. The end-result of these biological activities are oxygen rich surface waters with low concentrations of nutrients and metal ions and oxygen depleted bottom waters with higher concentrations of nutrients and metal ions.     

Covariate model-based fault tree analysis for risk assessment in chemical process industries: A case study of a chlorine manufacturing facility

Fault tree analysis (FTA) is a promising quantitative technique for risk analysis in chemical process industries (CPIs). In FTA, a certain sequence of basic events (causes) leads to one specific Top event (critical event of interest). However, the conventional fault tree analysis has the limitations of staticity and uncertainty. The staticity in conventional FTA arises due to its inability to accommodate time-dependent characteristics of the process system. Whereas uncertainty primarily lies in the failure probability data of basic events. This paper proposes an innovative methodology that uses a time-dependent covariate model to update the failure probability values of major contributing basic events in FTA. A novel subclass of the family of phase-type distributions is used to model the covariates corresponding to the basic events. The newly developed methodology is applied for a case study in a chlorine manufacturing facility to estimate the chlorine release probability. The blockage in the pipeline was identified as the significant reason for chlorine release from expert opinion and sensitivity analysis. The results of the proposed model of FTA are compared with that of conventional FTA.     

固相萃取-气相色谱-串联质谱法同时测定武汉市普通人群血清中35种有机氯农药与多氯联苯

有机氯农药(OCPs)和多氯联苯(PCBs)是两类重要的持久性有机污染物,可在环境介质中长期存在,并通过多种途径进入人体,导致人体的高暴露风险。OCPs和PCBs对人体存在诸多健康危害,精准定量人体内OCPs和PCBs的暴露水平是健康效应评价的关键。该研究基于固相萃取-气相色谱-串联质谱联用技术(SPE-GC-MS/MS)建立了同时检测100 μL血清中35种OCPs和PCBs的分析方法。血清样品经尿素沉淀蛋白后,采用Oasis^® HLB小柱净化,正己烷-二氯甲烷混合溶液(1∶1, v/v)洗脱,氮吹近干,正己烷定容,多反应监测(MRM)模式检测,内标法定量分析。结果表明,OCPs和PCBs在0.05~50.0 ng/mL范围内线性关系良好,检出限在1.2~71.4 ng/L之间。35种目标分析物的加标回收率在72.6%~142%之间,相对标准偏差小于25%。利用所建立的方法检测了武汉市普通人群血清样本中OCPs和PCBs的浓度水平,结果表明武汉市普通人群广泛暴露于OCPs和PCBs,且以OCPs为主。有8种OCPs和7种PCBs检出率高于50%,其中p,p'-滴滴伊、p,p'-滴滴滴和甲氧滴滴涕检出率达100%,非类二噁英PCBs是PCBs的主要成分。血清中OCPs浓度随年龄增长呈升高趋势,在60岁以上存在性别差异;不同性别、年龄人群血清中PCBs浓度无统计学差异。该方法样本用量少,操作简便,具有较高的准确度和精密度,适用于环境健康研究中大量人群血清样本中痕量OCPs和PCBs的生物监测。     

混凝土破裂过程的三维数值模型

利用混合同余法产生了随机变量,将混凝土中的骨料简化为球体,采用循环比较法将随机变量赋给球心坐标(X,Y,Z),实现了混凝土骨料的空间随机分布,最终建立了三维混凝土数值模型。对模型整体进行单元剖分,将骨料、砂浆、界面层分别投影到该有限元网格中,采用多次网格划分技术完成模型网格划分。通过对算例进行有限元计算,结果表明该模型基本上反映了混凝土骨料分布的实际情况,较好地模拟了混凝土的不均匀性与各向异性,验证了建立该模型的方法是可行的。     

圆盘离心沉降法测定固体粉末的粒度分布

本文报道用圆盘离心沉降法对几种粉末样品的粒径大小及粒度分布测定的结果,并且讨论了颗粒形状、消光系数和粉末分散状态等因素的影响。试验结果表明,在给定的条件下,利用LKY-1型微粒测定仪对粉末粒度测定的重复性好,尤其适用于测定微细粉末的粒度分布;当石墨或MoS_2粉末样品的浓度为0.5％时,选用4％鞣酸作分散剂的效果最好。作者认为,固然光密度与微粒的消光系数有关,但对于黑灰色的粉末样品而言,因其产生的光学效应非常微弱,故可近似地把消光系数视为常数而忽略它的影响。     

Steady-State Source Flow in Heterogeneous Porous Media

The flow of fluids in heterogeneous porous media is modelled by regarding the hydraulic conductivity as a stationary random space function. The flow variables, the pressure head and velocity field are random functions as well and we are interested primarily in calculating their mean values. The latter had been intensively studied in the past for flows uniform in the average. It has been shown that the average Darcy's law, which relates the mean pressure head gradient to the mean velocity, is given by a local linear relationship. As a result, the mean head and velocity satisfy the local flow equations in a fictitious homogeneous medium of effective conductivity. However, recent analysis has shown that for nonuniform flows the effective Darcy's law is determined by a nonlocal relationship of a convolution type. Hence, the average flow equations for the mean head are expressed as a linear integro-differential operator. Due to the linearity of the problem, it is useful to derive the mean head distribution for a flow by a source of unit discharge. This distribution represents a fundamental solution of the average flow equations and is called the mean Green function G _d (x). The mean head G _d(x) is derived here at first order in the logconductivity variance for an arbitrary correlation function (x) and for any dimensionality d of the flow. It is obtained as a product of the solution G _d ⁽⁰⁾(x) for source flow in unbounded domain of the mean conductivity K _A and the correction _d (x) which depends on the medium heterogeneous structure. The correction _d is evaluated for a few cases of interest.Simple one-quadrature expressions of _d are derived for isotropic two- and three-dimensional media. The quadratures can be calculated analytically after specifying (x) and closed form expressions are derived for exponential and Gaussian correlations. The flow toward a source in a three-dimensional heterogeneous medium of axisymmetric anisotropy is studied in detail by deriving ₃ as function of the distance from the source x and of the azimuthal angle . Its dependence on x, on the particular (x) and on the anisotropy ratio is illustrated in the plane of isotropy (=0) and along the anisotropy axis ( = /2).The head factor k ^* is defined as a ratio of the head in the homogeneous medium to the mean head, k ^*=G _d ⁽⁰⁾/G _d= _d ^–1. It is shown that for isotropic conductivity and for any dimensionality of the flow the medium behaves as a one-dimensional and as an effective one close and far from the source, respectively, that is, lim _x0 k ^*(x) = K _H/K _A and lim _x k ^*(x) = K ^efu/K _A, where K _A and K _H are the arithmetic and harmonic conductivity means and K ^efu is the effective conductivity for uniform flow. For axisymmetric heterogeneity the far-distance limit depends on the direction. Thus, in the coordinate system of (x) principal directions the limit values of k ^* are obtained as . These values differ from the corresponding components of the effective conductivities tensor for uniform flow for = 0 and /2, respectively. The results of the study are applied to solving the problem of the dipole well flow. The dependence of the mean head drop between the injection and production chambers on the anisotropy of the conductivity and the distance between the chambers is analyzed.     

Defect assessment procedure based on ductile tearing process

Strain hardening, crack growth resistance and nonuniform load distribution have significant effects on the ductile tearing process. A defect assessment procedure incorporating with the above features is proposed in the present paper, with the final appearance of “design curves” to facilitate engineering applications.     

PATH INTEGRAL SOLUTION OF NONLINEAR DYNAMIC BEHAVIOR OF STRUCTURE UNDER WIND EXCITATION

IntroductionThe dynamic behavior of the nonlinear structure under wind excitation has beenobserved very complicated.Taking guyed masts as an example,only a few collapsingaccidents occurred under extreme atmospheric conditions[1],many took place under mild…     

基于高阶位移模式的压电层合板动力有限元模型

建立了含压电片层合板的有限元动力学模型。以位于压电层上下表面处的电场强度和层间电压为未知量,给出了三次函数的电势分布模式,采用Reddy的高阶剪切理论描述板的位移场,假设板厚度方向的正应力为零给出了减缩的本构方程,采用有限元方法,基于Hamilton原理导出结构的动力学方程,然后用静态缩聚的方法压缩掉电场自由度和次要的位移自由度。最后用四边形矩形单元求解了一对称铺层和非对称铺层悬臂板的固有频率,并与ANSYS结果对比验证了本文模型的精确性。     

开区注氮采空区自燃温度场的数值模拟研究

为了研究开区注氮采空区遗煤自燃和被抑制的力学过程，用非均质多孔介质中的渗流连续性方程、气体弥散方程和综合传热方程的联立，建立了采空区注氮非定常数值模型．结合实例，用迎风格式有限元方法求解．给出了采空区的漏风流态、氮气流态，描绘了采空区自燃过程中氧、CO浓度和温度分布的变化过程．计算考虑了瓦斯涌出和工作面推进的影响．得到注氮条件下采空区高温区形状变窄；随着注氮量的提高，使自然发火期逐渐变长，直至不自燃．理论计算与实际情况吻合．